The study focuses on enhancing clean hydrogen production through microwave-driven water dissociation, with a particular emphasis on the impact of tungsten-based electrode materials and steam conditions. The research evaluates the hydrogen production process at both the dissociation level and the overall system efficiency. Lanthanated tungsten electrodes are identified as the most effective in enhancing hydrogen production, demonstrating superior performance compared to other materials like ceriated tungsten. The study shows a positive correlation between steam inlet temperature and hydrogen production, emphasizing the significance of operating at higher temperatures, with 120°C being the most optimal. Energy consumption for hydrogen production varies between 51.98 to 56.66 kWh/kg, with lanthanated tungsten electrodes showcasing the lowest energy requirement. The research also considers factors like energy and exergy efficiencies, where lanthanated tungsten electrodes exhibit the highest efficiencies at 120°C steam inlet temperature. Overall, the study concludes that lanthanated tungsten electrodes offer valuable implications for advancing microwave-driven hydrogen production technologies, pointing towards a cleaner and more efficient method of hydrogen generation.