Innovative Surface Reconstruction Strategy Enhances Non-Noble Metal Cathodes for Hydrogen Evolution Reaction
Key Ideas
- Researchers at Tohoku University developed a surface reconstruction strategy to improve hydrogen evolution reactions using non-noble metal cathodes.
- The cathodes demonstrated stable performance for over 300 hours and are expected to reach a cost close to the US Department of Energy's 2026 hydrogen production target.
- The study validated the enhanced catalytic activity of the cathodes in both laboratory setups and commercially relevant proton exchange membrane electrolyzers.
- The incorporation of fluorine into the cobalt phosphide lattice created additional active sites, accelerating the hydrogen evolution reaction, showcasing progress in non-precious metal-based catalyst research.
Researchers at Tohoku University have made significant progress in the field of hydrogen evolution reactions (HER) by developing a surface reconstruction strategy to enhance non-noble metal-based cathodes. The cathodes, specifically fluorine-modified cobalt phosphide, showed improved catalytic activity for over 300 hours, bringing the cost of hydrogen production close to the US Department of Energy's 2026 target. By incorporating fluorine into the cobalt phosphide lattice, the researchers created additional active sites that accelerated the HER, addressing the challenges of efficiency and slow kinetics.
The study published in Advanced Energy Materials focuses on transition metal phosphides (TMPs) as a promising avenue for improving HER performance due to their cost-effectiveness and durability. By filling the knowledge gap related to non-noble metals, the researchers aim to bridge the transition from laboratory-scale research to large-scale commercial production of clean hydrogen fuel.
Through operando X-ray absorption spectroscopy and Raman measurements, the team investigated the surface reconstruction and active sites of the fluorine-modified cobalt phosphide cathodes. The results indicated that the reconstructed cobalt was highly active in acidic conditions, demonstrating around 76 W of power output during the 300-hour stability test.
The successful validation of these findings in both laboratory and commercial electrolyzer setups marks a significant advancement in HER catalyst research. This development paves the way for designing cost-effective, non-precious metal-based cathodes that could contribute to the widespread adoption of hydrogen technology. The researchers emphasize the practical implications of their work, bringing them closer to realizing everyday applications in commercial proton exchange membrane electrolyzers.