Hydrogen energy, known for its efficiency and cleanliness, has attracted global interest. This article delves into the significance of high-performance membranes in alkaline water electrolysis (AWE) for green hydrogen production. While alkaline water electrolysis is considered cost-effective for industrial green hydrogen production, existing technology faces challenges in efficiency and cost compared to traditional methods. Researchers are focusing on enhancing AWE efficiency through catalyst exploration, membrane development, and operational improvements. The membrane's crucial role in AWE involves maintaining system safety while facilitating electrolyte flow and minimizing resistance. Recent advancements have seen the use of polyphenylene sulfide (PPS) fabric membranes in AWE, with efforts to improve hydrophilicity and gas barrier properties through functional coatings. The article introduces a novel approach to design a high-efficiency AWE membrane, PMCM-2, using a two-step method and a porous support layer. PMCM-2 demonstrates superior performance in electrolysis, durability, and industrial application suitability. Furthermore, a semi-empirical model has been proposed to optimize the PMCM-2-based electrolyzer system. This innovative development showcases the potential to enhance green hydrogen production through improved AWE membrane technology.